While Weak Law of Large Numbers is useful to understand the Convergence in Probability, it does not tell us how to give approximation to distribution of estimator. Asymptotic Approximation can be obtained by this, Convergence in Distribution.
Definition
Let be a random vector with cdf . We say that converges in distribution to , if
for all where is continuous.
We could denote as .
Intuitively, as becomes larger, the shape of the sample distribution of becomes closer to that of .
The very classical example is the Central Limit Theorem.